A Collection of Fullerenes for Synthetic Access Toward Oriented Charge-Transfer Cascades in Triple-Channel Photosystems
Autor: | Carmen Atienza, Stefan Matile, Santiago Lascano, Nazario Martín, Saeideh Soleimanpour, Naomi Sakai, Alatengbaolige Bolag, Javier López-Andarias |
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Rok vydání: | 2014 |
Předmět: |
Models
Molecular Fullerene Chemistry 010405 organic chemistry Hydrazones Supramolecular chemistry Charge (physics) Nanotechnology General Chemistry General Medicine 010402 general chemistry Functional system 01 natural sciences Catalysis Polymerization 0104 chemical sciences Electron Transport Charge transfer ddc:540 Fullerenes Photosystem Communication channel |
Zdroj: | Angew. Chem. Int. Ed. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Angewandte Chemie: International Edition, Vol. 53, No 19 (2014) pp. 4890-4895 Angewandte Chemie Repositorio Institucional del Instituto Madrileño de Estudios Avanzados en Nanociencia Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia) instname |
ISSN: | 0044-8249 1433-7851 |
DOI: | 10.1002/ange.201402042 |
Popis: | The development of synthetic methods to build complex functional systems is a central and current challenge in organic chemistry. This goal is important because supramolecular architectures of highest sophistication account for function in nature, and synthetic organic chemistry, contrary to high standards with small molecules, fails to deliver functional systems of similar complexity. In this report, we introduce a collection of fullerenes that is compatible with the construction of multicomponent charge-transfer cascades and can be placed in triple-channel architectures next to stacks of oligothiophenes and naphthalenediimides. For the creation of this collection, modern fullerene chemistry-methanofullerenes and 1,4-diarylfullerenes-is combined with classical Nierengarten-Diederich-Bingel approaches. |
Databáze: | OpenAIRE |
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