Bio-based and environmental input for transfer hydrogenation using EcoNi(0) catalyst in isopropanol
| Autor: | Guillaume Clavé, Nathalie Masquelez, Cyril Poullain, Peter Hesemann, Claude Grison, Eddy Petit, Vincent Escande |
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| Přispěvatelé: | Bio-inspired Chemistry and Ecological Innovations (ChimEco), Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Institut Européen des membranes (IEM), Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Green chemistry
Reducing agent Nanoparticle 010501 environmental sciences Transfer hydrogenation 7. Clean energy 01 natural sciences Catalysis 12. Responsible consumption chemistry.chemical_compound Organic chemistry Formate Sustainable chemistry 0105 earth and related environmental sciences General Environmental Science Reduction 010405 organic chemistry Chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Process Chemistry and Technology Thermal decomposition Phytoextraction [CHIM.CATA]Chemical Sciences/Catalysis 0104 chemical sciences Bio-sourced catalyst 13. Climate action Ecocatalysis Selectivity |
| Zdroj: | Applied Catalysis B: Environmental Applied Catalysis B: Environmental, Elsevier, 2017, 210, pp.495-503. ⟨10.1016/j.apcatb.2017.04.023⟩ |
| ISSN: | 0926-3373 |
| Popis: | International audience; The transfer hydrogenation of carbonyl compounds into alcohols with isopropanol has emerged as agreen alternative to the use of hazardous reducing agents. Ni(0) nanoparticles have been described asan efficient catalyst for this reaction, while their classical preparation is still associated with a numberof safety and environmental concerns. Here, we report a sustainable, ecological and straightforwardpreparation of a biosourced Ni(0) based material, by thermal decomposition of Ni(II) formate made from aNi hyperaccumulating plant. The resulting catalyst, EcoNi(0), shows high catalytic activity and selectivityfor the transfer hydrogenation of carbonyl compounds, including challenging aldehydes. The processseeks to be an incentive for the economic development of phytoextraction. |
| Databáze: | OpenAIRE |
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