Production and Characterization of Molecular Dications: Experimental and Theoretical Efforts
| Autor: | Marzio Rosi, Stefano Falcinelli |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Molecular dications
Astrochemistry Research groups Coulomb explosion Molecular Conformation Pharmaceutical Science Electrons Review 02 engineering and technology 010402 general chemistry Electron-ion-ion coincidence technique 01 natural sciences Analytical Chemistry lcsh:QD241-441 Molecular level lcsh:Organic chemistry Ab initio quantum chemistry methods Cations Metals Alkaline Earth Drug Discovery Polycyclic Aromatic Hydrocarbons Physical and Theoretical Chemistry Propellant Kinetic energy released Mass spectrometry Atmosphere Organic Chemistry Benzene 021001 nanoscience & nanotechnology Molecular beam 0104 chemical sciences Characterization (materials science) Kinetics Chemistry (miscellaneous) Chemical physics Potential energy surfaces Thermodynamics Molecular Medicine Ab initio calculations Ion escape 0210 nano-technology Planetary atmospheres |
| Zdroj: | Molecules Molecules, Vol 25, Iss 4157, p 4157 (2020) |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/molecules25184157 |
| Popis: | Molecular dications are doubly charged cations of importance in flames, plasma chemistry and physics and in the chemistry of the upper atmosphere of Planets. Furthermore, they are exotic species able to store a considerable amount of energy at a molecular level. This high energy content of several eV can be easily released as translational energy of the two fragment monocations generated by their Coulomb explosion. For such a reason, they were proposed as a new kind of alternative propellant. The present topic review paper reports on an overview of the main contributions made by the authors’ research groups in the generation and characterization of simple molecular dications during the last 40 years of coupling experimental and theoretical efforts. |
| Databáze: | OpenAIRE |
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