3-(4-Chlorophenylsulfonyl)-2-methylnaphtho[1,2-b]furan

Autor:	Byeng Wha Son, Uk Lee, Pil Ja Seo, Hong Dae Choi
Rok vydání:	2008
Předmět:	Crystallography General Chemistry Crystal structure Dihedral angle Condensed Matter Physics Bioinformatics Ring (chemistry) Organic Papers Medicinal chemistry chemistry.chemical_compound chemistry QD901-999 Furan General Materials Science Benzene
Zdroj:	Acta Crystallographica Section E, Vol 64, Iss 5, Pp o837-o837 (2008) Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
Popis:	The title compound, C19H13ClO3S, was prepared by the oxidation of 3-(4-chlorophenylsulfanyl)-2-methylnaphtho[1,2-b]furan with 3-chloroperoxybenzoic acid. The 4-chlorophenyl ring makes a dihedral angle of 68.59 (5)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by π–π interactions between the benzene rings of neighbouring molecules [centroid–centroid distance = 3.635 (3) Å], and by C—H...π interactions between a methyl H atom and the furan ring of an adjacent molecule. In addition, the crystal structure exhibits intermolecular C—H...O interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::272502f6ddff5ebf893844490d68226a https://doi.org/10.1107/s1600536808009215 Zobrazit plný text záznamu