Multianalyte voltammetric determination of traffic-linked metals in marine organisms employed as pollution bio-monitors
| Autor: | Alessandro Zappi, Clinio Locatelli, Sonia Casolari, Dora Melucci, Francesco De Laurentiis |
|---|---|
| Přispěvatelé: | Locatelli C., Melucci D., De Laurentiis F., Zappi A., Casolari S. |
| Rok vydání: | 2020 |
| Předmět: |
Pollution
spectroscopy toxic metals Health Toxicology and Mutagenesis media_common.quotation_subject mussel Inorganic chemistry Soil Science chemistry.chemical_element Zinc 010501 environmental sciences 01 natural sciences Analytical Chemistry Rhodium Environmental Chemistry SWAdCSV Waste Management and Disposal clam 0105 earth and related environmental sciences Water Science and Technology media_common Cadmium Platinum Group Metals (PGMs) 010401 analytical chemistry Public Health Environmental and Occupational Health Copper 0104 chemical sciences chemistry Platinum Palladium |
| Zdroj: | International Journal of Environmental Analytical Chemistry. 102:1563-1582 |
| ISSN: | 1029-0397 0306-7319 |
| DOI: | 10.1080/03067319.2020.1739665 |
| Popis: | A new procedure is proposed for the voltammetric determination of ultra-trace cadmium(II), copper(II), lead(II), platinum(II), palladium(II), rhodium(III) and zinc(II) by a single run of square wave adsorptive catalytic stripping voltammetry. The voltammetric cell was based on a typical three-electrodes set-up: working electrode (stationary hanging mercury drop), reference electrode (Ag|AgCl|KClsat) and auxiliary electrode (platinum). The supporting electrolyte contained the formazone complex together with dimethylglyoxime and the disodium salt of ethylenediaminetetraacetic acid. Validation of the analytical procedure was obtained by the analysis of standard reference materials (Mussel Tissue BCR-CRM 278, Oyster Tissue NIST-SRM 1566a). Comparison with spectroscopic measurements was performed. Good accuracy was achieved. The analytical procedure was finally applied to mussels and clams sampled on the mouth of Po river, employed as bio-monitors. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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