Tandem Catalysis of Amines Using Porous Graphene Oxide

Autor:	Kapil Pareek, Kian Ping Loh, Janardhan Balapanuru, Rika Tandiana, Tamio Hayashi, Wei Tang, Chenliang Su, Chang Tai Nai
Rok vydání:	2015
Předmět:	Primary (chemistry) Tandem Chemistry Porous graphene Oxide General Chemistry Bond formation Biochemistry Combinatorial chemistry Catalysis Bifunctional catalyst chemistry.chemical_compound Colloid and Surface Chemistry Organic chemistry Oxidative coupling of methane
Zdroj:	Journal of the American Chemical Society. 137:685-690
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja512470t
Popis:	Porous graphene oxide can be used as a metal-free catalyst in the presence of air for oxidative coupling of primary amines. Herein, we explore a GO-catalyzed carbon-carbon or/and carbon-heteroatom bond formation strategy to functionalize primary amines in tandem to produce a series of valuable products, i.e., α-aminophosphonates, α-aminonitriles, and polycyclic heterocompounds. Furthermore, when decorated with nano-Pd, the Pd-coated porous graphene oxide can be used as a bifunctional catalyst for tandem oxidation and hydrogenation reactions in the N-alkylation of primary amines, achieving good to excellent yields under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2715445a1131ae51b5e6f12df08b3b30 https://doi.org/10.1021/ja512470t Zobrazit plný text záznamu