Titanium Germylidenes

Autor: Vladimir Ya. Lee, Ryo Sakai, Kazunori Takanashi, Olga A. Gapurenko, Ruslan M. Minyaev, Heinz Gornitzka, Akira Sekiguchi
Přispěvatelé: Graduate School of Pure and Applied Sciences, University of Tsukuba, Université de Tsukuba = University of Tsukuba, Southern Federal University [Rostov-on-Don] (SFEDU), Laboratoire de chimie de coordination (LCC), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Rok vydání: 2021
Předmět:
Zdroj: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2021, 60 (8), pp.3951-3955. ⟨10.1002/anie.202015704⟩
ISSN: 1521-3757
0044-8249
1433-7851
1521-3773
DOI: 10.1002/ange.202015704
Popis: International audience; Two novel 18‐electron titanium germylene complexes, Cp2Ti(L)=Ge[Si3(SiMetBu2)4] 3 b (L=Me3P) and 3 c (L=XylNC), were synthesized, isolated, and structurally characterized. The length of the titanium‐germanium bonds of 2.5387(3) Å and 2.5276(3) Å (in 3 b and 3 c, respectively) well match those expected for the double bond, which was further supported by the DFT study. Based on their structural characteristics, as well as their atomic charges calculations which revealed Ti(δ+)=Ge(δ−) bond polarization, both 3 b and 3 c are classified as the Schrock‐type titanium germylidenes, as the germanium analogues of the widely known titanium alkylidenes. By contrast, germylene complexes of the group 6 metals 8 a (M=Mo) and 8 b (M=W) are better described as Fischer‐type germylene complexes.
Databáze: OpenAIRE
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