Synthesis and reactivity of a μ-1,2-dinitrogen dinickel(II) complex with a C-H activated silaamidinate pincer ligand

Autor:	Chaopeng Hu, Yazhou Ding, Yunping Bai, Lulu Guo, Chunming Cui
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). 58(99)
ISSN:	1364-548X
Popis:	The first stable dinuclear Ni(ii) dinitrogen complex 2 has been prepared via the intramolecular C–H activation of one isopropyl group in the ligand. The coordinated N2 could be replaced by CO and isocyanide, indicating the weakly activated N2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::26cadf4fc0ce8ef9e0583fa4117002e4 https://pubmed.ncbi.nlm.nih.gov/36441626 Zobrazit plný text záznamu