p-Carborane: a New Cage Spacer for Photoactive Metal Polypyridine Dyads

Autor:	Marco Ghirotti, Maria Teresa Indelli, Claudio Chiorboli, Peter F. H. Schwab, Franco Scandola
Jazyk:	angličtina
Rok vydání:	2006
Předmět:	Stereochemistry chemistry.chemical_element Bridging ligand Photoinduced electron transfer Ruthenium Inorganic Chemistry Metal Bipyridine chemistry.chemical_compound Crystallography chemistry visual_art visual_art.visual_art_medium Carborane Partial oxidation Physical and Theoretical Chemistry Cage
Zdroj:	Inorganic chemistry 45 (2006): 4331–4333. doi:10.1021/ic060327m info:cnr-pdr/source/autori:Marco Ghirotti; Peter F. H. Schwab; M. Teresa Indelli; Claudio Chiorboli; Franco Scandola./titolo:p-Carborane: a New Cage Spacer for Photoactive Metal Polypyridine Dyads/doi:10.1021%2Fic060327m/rivista:Inorganic chemistry/anno:2006/pagina_da:4331/pagina_a:4333/intervallo_pagine:4331–4333/volume:45
DOI:	10.1021/ic060327m
Popis:	The first example of a binuclear ruthenium complex involving the p-carborane framework in the bridging ligand is reported. The bridging ligand is a symmetric linear array comprising a central p-carborane unit, two p-phenylene spacers, and two 5-yl-2,2'-bipyridine coordinating units. A homobinuclear Ru(II) complex, with 2,2'-bipyridine as peripheral ligands, was synthesized and characterized. The Ru(II)-Ru(III) mixed-valence species, obtained by partial oxidation, has been investigated with steady-state and time-resolved techniques in CH3CN. The rate of photoinduced electron transfer is 2.3 x 10(8) s(-1).
Databáze:	OpenAIRE
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