Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions
| Autor: | Bo-Wen Hu, Mir Wais Hosseini, Sylvie Ferlay, Nathalie Gruber-Kyritsakas |
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| Přispěvatelé: | School of Chemical Engineering and Technology, Harbin Institute of Technology, 150001 Harbin, People’s Republic of ChinacUniversity, Chimie de la matière complexe (CMC), Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2018 |
| Předmět: |
Structural phase
Materials science Hydrogen 010405 organic chemistry Hydrogen bond Bisamidinium Value (computer science) chemistry.chemical_element General Chemistry [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry Condensed Matter Physics 01 natural sciences Honeycomb like 0104 chemical sciences Crystallography chemistry Thermal [CHIM.CRIS]Chemical Sciences/Cristallography [CHIM]Chemical Sciences General Materials Science Solid solution |
| Zdroj: | CrystEngComm CrystEngComm, Royal Society of Chemistry, 2018, 20 (13), pp.1853-1861. ⟨10.1039/C8CE00023A⟩ |
| ISSN: | 1466-8033 |
| Popis: | International audience; Solid solution of Hydrogen bonded networks of formula ((1-2H +)3x(2-2H +)3(1-x)([Fe(CN)6] 3-2)). nH2O, where (1-2H +) and (1-2H +) are bisamidinium H bond donor entities, have been synthetized and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different pavages of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H +) have been performed, evidencing H bonding between adjacent cations. Thermal properties of the solid solutions have been performed. |
| Databáze: | OpenAIRE |
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