Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

Autor:	Mariia Lemishka, Edyta Tabor, Jiri Dedecek, Kinga Mlekodaj, Stepan Sklenak
Rok vydání:	2021
Předmět:	Inorganic chemistry Metals and Alloys General Chemistry Catalysis Methane Surfaces Coatings and Films Electronic Optical and Magnetic Materials Gas phase chemistry.chemical_compound Ferrierite chemistry Transition metal Materials Chemistry Ceramics and Composites Methanol Zeolite Effluent
Zdroj:	Chemical Communications. 57:3472-3475
ISSN:	1364-548X 1359-7345
Popis:	Here we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2677d3025084e98cdaaf131bb1406eb4 https://doi.org/10.1039/d1cc00909e Zobrazit plný text záznamu