Alternatively Modified Bingel Reaction for Efficient Syntheses of C60 Hexakis-Adducts

Autor:	Huaping Li, and Maria Torres-Castillo, Mohammed J. Meziani, Ya-Ping Sun, Alex Kitaygorodskiy, Sk. Anwarul Haque
Rok vydání:	2007
Předmět:	Fullerene derivatives Chemistry Organic Chemistry Polymer chemistry Organic chemistry General Medicine Bingel reaction Physical and Theoretical Chemistry Biochemistry Adduct
Zdroj:	ChemInform. 38
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200714118
Popis:	It was found that the C60 hexakis-adduct (Th) bearing 12 electron-donating N,N-dimethylaniline moieties could not be synthesized by the Bingel-Hirsch method with either classical or deviated experimental parameters in a one-pot reaction. A different modification to the original Bingel reaction without the use of any templating agent was necessary for high-yield synthesis of the compound. The generalization of this alternatively modified Bingel method to the preparation of other C60 hexakis-adducts is demonstrated. [structure: see text].
Databáze:	OpenAIRE
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