Synthesis, structure and photocatalytic property of a novel Zn(II) coordination polymer based on in situ synthetized pyridine-3,4-dicarboxylhydrazidate ligand
| Autor: | Shu-Yue Wu, Qing-An Qiao, Yuan-Hong Lu, Yu-Chang Wang, Han-Shu Li, Wenfu Yan, Qin-Jun Zhang, Shang-Fan Ping, Zheng-Yan Jiang, Juan Jin |
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| Rok vydání: | 2020 |
| Předmět: |
Photoluminescence
Coordination polymer Ligand 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics Hydrothermal circulation 0104 chemical sciences Analytical Chemistry Catalysis chemistry.chemical_compound chemistry Polymer chemistry Pyridine Photocatalysis Molecule 0210 nano-technology Instrumentation Spectroscopy |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 233:118232 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2020.118232 |
| Popis: | One new pyridine-3,4-dicarboxylhydrazidate-coordinated compound [Zn(pdh)] 1 (pdh = pyridine-3,4-dicarboxylhydrazidate) was obtained under the hydrothermal conditions. Noteworthily, the pdh molecules in the title compound originated from the ligand in situ reaction between organic pyridine-3,4-dicarboxylic acid (pdca) and N2H4·H2O. X-ray single-crystal diffraction analysis revealed that the pdh ligands exhibit a special μ4-bridging mode in compound 1, which link Zn(II) centers into a 2D layered structure. The photocatalysis analysis indicates that it is a potential visible light catalyst. In addition, the solid photoluminescence property of compound 1 was also investigated. |
| Databáze: | OpenAIRE |
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