Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
| Autor: | Petr A. Zhmurov, Aleksandr O. Kokuev, Yulia V. Nelyubina, Vladimir A. Tartakovsky, Alexey Yu. Sukhorukov, Artem N. Semakin, Sema L. Ioffe |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Tris
azoalkenes 010405 organic chemistry hydrazone ligands Organic Chemistry 010402 general chemistry α-halogen hydrazones 01 natural sciences Medicinal chemistry Full Research Paper 0104 chemical sciences lcsh:QD241-441 Chemistry Ammonia chemistry.chemical_compound heterocage compounds chemistry lcsh:Organic chemistry Intramolecular force Michael addition Organic chemistry Amine gas treating lcsh:Q lcsh:Science Derivative (chemistry) |
| Zdroj: | Beilstein Journal of Organic Chemistry, Vol 12, Iss 1, Pp 2471-2477 (2016) Beilstein Journal of Organic Chemistry |
| ISSN: | 1860-5397 |
| Popis: | Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines – a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|