New Perylene Diimide Ink for Interlayer Formation in Air-Processed Conventional Organic Photovoltaic Devices
Autor: | Mahmoud E. Farahat, Michael A. Anderson, Mark Martell, Erin L. Ratcliff, Gregory C. Welch |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | ACS Applied Materials & Interfaces. 14:43558-43567 |
ISSN: | 1944-8252 1944-8244 |
DOI: | 10.1021/acsami.2c12281 |
Popis: | Roll-to-roll coating of conventional organic photovoltaic architectures in air necessitates low work function, electron-harvesting interlayers as the top interface, termed cathode interlayers. Traditional materials based on metal oxides are often not compatible with coating in air and/or green solvents, require thermal annealing, and are limited in feasibility due to interactions with underlying layers. Alternatively, perylene diimide materials offer easily tunable redox properties, are amenable to air coating in green solvents, and are considered champion organic-based cathode interlayers. However, underlying mechanisms of the extraction of photogenerated electrons are less well understood. Herein, we demonstrate the utilization of two |
Databáze: | OpenAIRE |
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