Hydrothermal liquefaction of Syrian mesquite (Prosopis farcta): Effects of operating parameters on product yields and characterization by different analysis methods
Autor: | Utku Çolak, Halil Durak, Salih Genel |
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Rok vydání: | 2018 |
Předmět: |
020209 energy
General Chemical Engineering Sodium chemistry.chemical_element 02 engineering and technology 010501 environmental sciences Raw material Condensed Matter Physics 01 natural sciences Catalysis Hydrothermal liquefaction chemistry Elemental analysis 0202 electrical engineering electronic engineering information engineering Proton NMR Physical and Theoretical Chemistry Prosopis farcta Analysis method 0105 earth and related environmental sciences Nuclear chemistry |
Zdroj: | The Journal of Supercritical Fluids. 140:53-61 |
ISSN: | 0896-8446 |
Popis: | In this study, the effect of temperature and catalyst on hydrothermal liquefaction of biomass was investigated. At the end of the experiments, prosopis farcta plant was transformed to solid residue (bio-char) and liquid products (heavy bio-oil, light bio-oil) at temperatures of 250, 300 and 350 °C with catalyst (H3BO3, Na2B4O7·10H2O, NaOH) and without catalyst by hydrothermal liquefaction. The liquid and solid products obtained at the end of the experiments were analyzed by GC–MS, FT-IR, 1 H NMR, SEM and elemental analysis methods. The highest liquid product yield was obtained at 350 °C with sodium tetraborate catalyst as 35.69%. According to the elemental analysis results, the HHV values of the liquid products range from 19.75 to 29.54 MJ kg−1 for 300 °C and from 18.06 to 30.02 MJ kg−1 for 350 °C. HHV values of all obtained liquid products were found to be higher than raw materials. |
Databáze: | OpenAIRE |
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