Soft particles in an electric field - a zero average contrast study
Autor: | Sofi Nöjd, Christopher Hirst, Priti S. Mohanty, Aurel Radulescu, Julien Schmitt, Marc Obiols-Rabasa, Peter Schurtenberger |
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Přispěvatelé: | Division of Physical Chemistry, Department of Chemistry, Lund University, SE-22100 Lund, Sweden, Julich Centre for Neutron Science, Heinz Maier-Leibnitz Zentrum, Garching, Germany, School of Chemical Technology, Kaligan Institute of Industrial Technology (KIIT), Bhubaneswar, India, Lund Institute of advanced Neutron and X-ray Science (LINXS), Lund University, Lund, Sweden |
Rok vydání: | 2019 |
Předmět: |
Physics
11 PM This article is licensed under a Creative Commons Attribution-NonCommercial 3 Field (physics) Condensed matter physics Ionic bonding 02 engineering and technology General Chemistry Neutron scattering 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Electric field Particle ddc:530 0 Unported Licence View Article Online Particle size 0210 nano-technology Structure factor Intensity (heat transfer) |
Zdroj: | Soft Matter Soft Matter, Royal Society of Chemistry, 2019, 15 (31), pp.6369-6374. ⟨10.1039/C9SM01208G⟩ Soft matter 15(31), 6369-6374 (2019). doi:10.1039/C9SM01208G |
ISSN: | 1744-6848 1744-683X |
DOI: | 10.1039/C9SM01208G⟩ |
Popis: | International audience; We report on the structural properties of ionic microgel particles subjected to alternating electric fields, using small-angle neutron scattering. The experiments were performed under so-called zero average contrast conditions, which cancel the structure factor contribution to the scattered intensity, allowing us to obtain direct information on the single particle size and structure as particles align in field-induced strings. Our results reveal only a marginal compression of the particles as they align in strings, and indicate considerable particle overlap at higher field strengths. These findings provide further insight into the origins of the previously reported unusual path dependent field-induced crystal-crystal transition found for these systems (P. S. Mohanty et al., Phys. Rev. X, 2015, 5, 011030) |
Databáze: | OpenAIRE |
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