Soft particles in an electric field - a zero average contrast study

Autor: Sofi Nöjd, Christopher Hirst, Priti S. Mohanty, Aurel Radulescu, Julien Schmitt, Marc Obiols-Rabasa, Peter Schurtenberger
Přispěvatelé: Division of Physical Chemistry, Department of Chemistry, Lund University, SE-22100 Lund, Sweden, Julich Centre for Neutron Science, Heinz Maier-Leibnitz Zentrum, Garching, Germany, School of Chemical Technology, Kaligan Institute of Industrial Technology (KIIT), Bhubaneswar, India, Lund Institute of advanced Neutron and X-ray Science (LINXS), Lund University, Lund, Sweden
Rok vydání: 2019
Předmět:
Zdroj: Soft Matter
Soft Matter, Royal Society of Chemistry, 2019, 15 (31), pp.6369-6374. ⟨10.1039/C9SM01208G⟩
Soft matter 15(31), 6369-6374 (2019). doi:10.1039/C9SM01208G
ISSN: 1744-6848
1744-683X
DOI: 10.1039/C9SM01208G⟩
Popis: International audience; We report on the structural properties of ionic microgel particles subjected to alternating electric fields, using small-angle neutron scattering. The experiments were performed under so-called zero average contrast conditions, which cancel the structure factor contribution to the scattered intensity, allowing us to obtain direct information on the single particle size and structure as particles align in field-induced strings. Our results reveal only a marginal compression of the particles as they align in strings, and indicate considerable particle overlap at higher field strengths. These findings provide further insight into the origins of the previously reported unusual path dependent field-induced crystal-crystal transition found for these systems (P. S. Mohanty et al., Phys. Rev. X, 2015, 5, 011030)
Databáze: OpenAIRE