Physical and Physicochemical Stimuli-Responsive Arene Ruthenium Metallaprism
| Autor: | Mona A. Furrer, Julien Furrer, Bruno Therrien |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Stimuli responsive 010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Ruthenium Inorganic Chemistry Solvent Polymer chemistry Organic chemistry Physical and Theoretical Chemistry Alkyl |
| Zdroj: | Organometallics |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om300038g |
| Popis: | A stimuli responsive metalla prism composed of six p cymene ruthenium corners bridged by 3 undecyl 14 benzoquinonato 25 diolato ligands and connected by triangular 246 tri(pyridin 4 yl) 135 triazine panels has been synthesized and characterized. In solution the nature of the solvent as well as the temperature dictates the conformation of the metalla prism: The alkyl chains can either point away from the metalla prism or hide in the hydrophobic environments of the metalla prism. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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