Spectroelectrochemical and Computational Analysis of a Series of Cycloaddition–Retroelectrocyclization-Derived Donor–Acceptor Chromophores

Autor:	Susannah D. Banziger, Benjamin M. Oxley, Reese A. Clendening, Tong Ren
Rok vydání:	2020
Předmět:	Nonlinear optical Materials science Series (mathematics) Materials Chemistry Computational analysis Physical and Theoretical Chemistry Chromophore Donor acceptor Photochemistry Cycloaddition Surfaces Coatings and Films
Zdroj:	The Journal of Physical Chemistry B. 124:11901-11909
ISSN:	1520-5207 1520-6106
DOI:	10.1021/acs.jpcb.0c09450
Popis:	The [2+2] cyclcoaddition (CA) and subsequent retroelectrocyclization (RE) reactions are useful in constructing nonplanar donor-acceptor chromophores that exhibit nonlinear optical properties and intramolecular charge-transfer transitions. However, both the infrared (IR) and visible-near IR (vis-NIR) spectroelectrochemical responses of CA-RE-derived chromophores are rarely explored in depth. Reported in this contribution is a comprehensive IR and vis-NIR spectroelectrochemical study of the CA-RE adducts of DMAP-C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::251c7edfb96d82626856aff757435408 https://doi.org/10.1021/acs.jpcb.0c09450 Zobrazit plný text záznamu