Preparation and Reactivity of Biomass-Derived Dihydro-Dioxins
| Autor: | Karl Kempf, Daniel M. Miles-Barrett, Tomas Lebl, James R. D. Montgomery, Oxana Kempf, Nicholas J. Westwood |
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| Přispěvatelé: | University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM, University of St Andrews. Biomedical Sciences Research Complex |
| Rok vydání: | 2018 |
| Předmět: |
General Chemical Engineering
Hetereocycles NDAS Biomass 02 engineering and technology engineering.material 010402 general chemistry Renewable monomers 01 natural sciences Lignin Catalysis chemistry.chemical_compound Environmental Chemistry Organic chemistry General Materials Science Reactivity (chemistry) QD SDG 7 - Affordable and Clean Energy Dihydro-dioxin Depolymerization fungi food and beverages Depolymerisation 021001 nanoscience & nanotechnology QD Chemistry 0104 chemical sciences General Energy Monomer chemistry engineering Degradation (geology) Biopolymer 0210 nano-technology |
| Zdroj: | Westwood, N J, Montgomery, J, Kempf, K, Miles-Barrett, D, Kempf, O & Lebl, T 2018, ' Preparation and Reactivity of Biomass-derived dihydro-Dioxins ', Chemsuschem . https://doi.org/10.1002/cssc.201802109 |
| ISSN: | 1864-564X |
| DOI: | 10.1002/cssc.201802109 |
| Popis: | This work was supported by EPSRC PhD studentships EP/1654168 (JRDM) and EP/1518175 (DMMB) and the Industrial Biotechnology Innovation Centre (DMMB). The depolymerisation of the biopolymer lignin can give pure aromatic monomers but selective catalytic approaches remain scarce. Here, an approach was re-routed to deliver an unusual phenolic monomer. This monomer’s instability proved challenging but a degradation study identified strategies to overcome this. Heterocycles and a useful synthetic intermediate were prepared. The range of aromatics available from the b-O-4 unit in lignin was extended. Postprint |
| Databáze: | OpenAIRE |
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