Nanostructures in Te/Sb/Ge/Ag (TAGS) Thermoelectric Materials Induced by Phase Transitions Associated with Vacancy Ordering

Autor: Stefan A. Maier, Markus Nentwig, Oliver Oeckler, Tobias Rosenthal, G. Jeffrey Snyder, Nadja Giesbrecht, Heng Wang, Thorsten Schröder
Rok vydání: 2014
Předmět:
Zdroj: Inorganic Chemistry. 53:7722-7729
ISSN: 1520-510X
0020-1669
Popis: Te/Sb/Ge/Ag (TAGS) materials with rather high concentrations of cation vacancies exhibit improved thermoelectric properties as compared to corresponding conventional TAGS (with constant Ag/Sb ratio of 1) due to a significant reduction of the lattice thermal conductivity. There are different vacancy ordering possibilities depending on the vacancy concentration and the history of heat treatment of the samples. In contrast to the average α-GeTe-type structure of TAGS materials with cation vacancy concentrations
Databáze: OpenAIRE