A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2]12-: synthesis and structural characterisation of the bis-{Ru(p-cymene)}2+-containing anion [Sb2W20O70{Ru(p-cymene)}2]10
| Autor: | Anna Proust, Richard Villanneau, René Thouvenot, Danielle Laurencin, Yves Jeannin, Patrick Herson |
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| Přispěvatelé: | Laboratoire de Chimie Inorganique et Matériaux Moléculaires (CIM2), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2005 |
| Předmět: |
p-Cymene
010405 organic chemistry Stereochemistry polyoxotungstate Metals and Alloys chemistry.chemical_element General Chemistry [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Ruthenium chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites ruthenium organometallic oxides |
| Zdroj: | Chemical Communications Chemical Communications, Royal Society of Chemistry, 2005, pp.5524. ⟨10.1039/b510300b⟩ Chemical Communications, 2005, pp.5524. ⟨10.1039/b510300b⟩ |
| ISSN: | 1359-7345 1364-548X |
| Popis: | International audience; The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2]10- by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined Ru(II)-substituted heteropolytungstates. Its Na salt was isolated in 13% yield, the structure of which was determined by x-ray crystallography. |
| Databáze: | OpenAIRE |
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