Infiltration and inversion of holographically defined polymer photonic crystal templates by atomic layer deposition

Autor: Jeffrey S. King, Jan Scrimgeour, Elton Graugnard, Olivia M. Roche, Christopher J. Summers, David N. Sharp, Andrew J. Turberfield, Robert G. Denning
Jazyk: angličtina
Rok vydání: 2006
Předmět:
Zdroj: ADVANCED MATERIALS. 18(12)
ISSN: 1521-4095
0935-9648
Popis: The demonstration of a practical technology for 3D optical microfabrication is a vital step in the development of photonic-crystal-based optical signal processing. [1] However, the extension of the optical methods that dominate integrated electronic circuit fabrication to three dimensions is a formidable materials-processing challenge: such a process must be capable not only of sub-micrometer pattern definition in three dimensions, but also of the transfer of this pattern into a homogeneous dielectric with an appropriately high refractive index. In a companion paper, [2] we show that two optical methods, holographic lithography [3] and direct two-photon laser writing, [4–6] can be combined to create a rapid and flexible method for the definition of photonic crystal device structures in photoresist. In this communication, we report a further essential step towards the creation of devices operating within a full photonic bandgap: we have used atomic layer deposition (ALD), itself an established semiconductor processing technique, to create high-index TiO2 inverted replicas of holographically defined photonic crystals, followed by removal of the polymeric template by plasma etching. A range of techniques for 3D optical lithography has been demonstrated. A 3D photonic crystal structure can be written by holographic lithography, [3] which makes use of a periodic interference pattern generated by a multiple-beam interferometer to expose a thick layer of photoresist. 3D microstructures, both periodic and aperiodic, can also be generated by point-by-point exposure of the resist by two-photon absorption at a laser focus. [4–7] Two-photon laser writing is a serial process; point-by-point fabrication of a 3D photonic crystal is necessarily slower than holographic lithography, which is capable of defining the entire periodic structure in a single laser pulse. [3] The two techniques are complementary: two-photon laser writing can be used to modify a holographic exposure. [8] We have shown that, by imaging the distribution of photochemical change induced by holographic exposure, it is possible to align a subsequent two-photon exposure with the 3D photonic crystal lattice to achieve the precise registration that is required of a device structure embedded in a 3D photonic crystal. [2] This hybrid technique is rapid and flexible, but the polymeric resists used for 3D microfabrication have refractive indices n in the range 1.4–1.6, which is too low for most device applications. Devices based on waveguides and microcavities embedded within a photonic crystal [1] are designed to operate at frequencies within a complete (omnidirectional) photonic bandgap in order to suppress radiative loss; [9] to create a complete photonic bandgap, even in an optimized air-dielectric structure, a refractive contrast of at least 1.9 is necessary. [10–12]
Databáze: OpenAIRE
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