Solar Redox Flow Batteries with Organic Redox Couples in Aqueous Electrolytes: A Minireview
| Autor: | Wilson A. Smith, Kristina Wedege, Adélio Mendes, Anders Bentien, Dowon Bae |
|---|---|
| Přispěvatelé: | Faculdade de Engenharia |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
PH PHOTOCATHODE Flow (psychology) 9 10-ANTHRAQUINONE-2 6-DISULFONATE SEMICONDUCTOR Nanotechnology 02 engineering and technology Electrolyte 010402 general chemistry 01 natural sciences 7. Clean energy Redox SYSTEMS CELL Physical and Theoretical Chemistry Range (particle radiation) Aqueous solution ELECTROCHEMICAL ENERGY-STORAGE business.industry Photoelectrochemical cell PHOTOELECTROCHEMISTRY 021001 nanoscience & nanotechnology Solar energy Flow battery 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials CONVERSION General Energy LAYER 0210 nano-technology business |
| Zdroj: | Wedege, K, Bae, D, Smith, W A, Mendes, A & Bentien, A 2018, ' Solar Redox Flow Batteries with Organic Redox Couples in Aqueous Electrolytes : A Minireview ', Journal of Physical Chemistry C, vol. 122, no. 45, pp. 25729-25740 . https://doi.org/10.1021/acs.jpcc.8b04914 The Journal of Physical Chemistry C Repositório Científico de Acesso Aberto de Portugal Repositório Científico de Acesso Aberto de Portugal (RCAAP) instacron:RCAAP |
| ISSN: | 1932-7455 1932-7447 |
| Popis: | In recent years, research in solar energy storage with photoelectrochemical cells (i.e., solar redox flow batteries: SRFBs) has resurged. This development is emerging in parallel with the growing field of research into organic redox couples intended for aqueous redox flow batteries (RFBs) in a range of different pH environments. In a solar flow battery, the dissolved electroactive molecules are charged directly from solar radiation by semiconductor photoelectrodes. The charged solution can then at a later stage be converted into electricity, and solar flow batteries are as such an approach to build integrated solar energy generation and storage devices. Research in RFBs and SRFBs has from their beginning been mutually linked by use of the same organic redox molecules in the electrolyte, such as quinones. Despite the long research history (since 1976), metallic-based, acidic SRFBs have shown only incremental development, while research in the use of organic redox pairs appears more promising. This review focuses on the historical development of the use of organic redox pairs in both RFBs and SRFBs and in particular on the mutual exchange of methods and materials between the two fields. |
| Databáze: | OpenAIRE |
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