Hot-pressed polymer nanofiber supported graphene membrane for high-performance nanofiltration

Autor: Che Ning Yeh, Zhao Wang, Todd J. Menkhaus, Hao Fong, Jiaxing Huang, Rajesh Sahadevan
Rok vydání: 2017
Předmět:
Zdroj: Nanotechnology. 28:31LT02
ISSN: 1361-6528
0957-4484
DOI: 10.1088/1361-6528/aa7ba9
Popis: Graphene oxide (GO) sheets can be readily surface-overlaid on hot-pressed electrospun polyacrylonitrile (PAN) nanofiber membrane to form a continuous and crack-free layer; upon thermal reduction at 150 °C for 12 h, the resulting reduced GO (rGO) layer can reject ~90% MgSO4 with high water flux (due to the size exclusion mechanism), making the prepared PAN-rGO membranes promising nanofiltration media for water purification. It is important to note that no delamination of GO/rGO sheet layers has been observed throughout this study. We highlight that a simple processing method (i.e., hot pressing) is critical for the successful preparation of 2D materials (e.g., GO/rGO) based membranes/media. It is envisioned that the reported study can benefit many groups working on various membrane applications of 2D materials; in other words, the hot-pressed electrospun nanofiber membranes could be generally utilized as an innovative type of platform to support various 2D sheets for different separation applications such as highly efficient and cost-effective removal of dissolved components (e.g., organic molecules) and even (hydrated) ions from water.
Databáze: OpenAIRE