Separation and Characterization of Phenolic Compounds in Fennel (Foeniculum vulgare) Using Liquid Chromatography−Negative Electrospray Ionization Tandem Mass Spectrometry
| Autor: | Olga Jáuregui, Irene Parejo, Carles Codina, Ferran Sánchez-Rabaneda, Francesc Viladomat, Jaume Bastida |
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| Rok vydání: | 2004 |
| Předmět: |
Flavonoids
chemistry.chemical_classification Spectrometry Mass Electrospray Ionization Electrospray Chromatography Coumaric Acids Foeniculum biology Electrospray ionization Flavonoid General Chemistry Chemical Fractionation Tandem mass spectrometry biology.organism_classification Mass spectrometry Hydroxycinnamic acid chemistry.chemical_compound Phenols chemistry Glycosides General Agricultural and Biological Sciences Chromatography Liquid |
| Zdroj: | Journal of Agricultural and Food Chemistry. 52:3679-3687 |
| ISSN: | 1520-5118 0021-8561 |
| DOI: | 10.1021/jf030813h |
| Popis: | Liquid chromatography (LC) diode array detection (DAD) coupled to negative electrospray ionization (ESI) tandem mass spectrometry (MS/MS) was used for the rapid and sensitive identification of water-soluble phenolic compounds in fennel waste. The plant material was first extracted and then chromatographed on Sephadex LH-20 to afford seven fractions, each of them being subjected to LC-MS analysis. Identification of the compounds was carried out by interpretation of UV, MS, and MS/MS spectra. Forty-two phenolic substances were identified, 27 of which had not previously been reported in fennel, including hydroxycinnamic acid derivatives, flavonoid glycosides, and flavonoid aglycons. |
| Databáze: | OpenAIRE |
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