A simple method for routine measurement of organosulfur compounds in complex liquid and gaseous matrices
| Autor: | Margo Elzinga, Julian Zamudio, Sean van Boven kaarsmaker, Tonke van de Pol, Jan Klok, Annemiek ter Heijne |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
Chromatography
Gas WIMEK Sulfur Compounds Flame Photometric Detector (FPD) Volatile organosulfur compound (VOSC) Organic Chemistry General Medicine Biochemistry Analytical Chemistry Disulfide Gas chromatography (GC) Calibration Thiol Environmental Technology Milieutechnologie Gases Henry coefficient Biological Recovery & Re-use Technology |
| Zdroj: | Journal of Chromatography A 1677 (2022) Journal of Chromatography A, 1677 |
| ISSN: | 0021-9673 |
| DOI: | 10.1016/j.chroma.2022.463276 |
| Popis: | The measurement of VOSCs in complex matrices is challenging due to their volatile and reactive nature. A straightforward method using headspace chromatography was developed for routine analyses of organosulfur compounds in a high saline liquid matrix with a pH of 8.4. Direct sample acidification with a 1M acetate buffer (pH 3.6) showed an increased response for methanethiol, ethanethiol, propanethiol, dimethyl sulfide, dimethyl disulfide and diethyl disulfide. A good quadratic fit (R2 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect