EQCM Study of Influence of Anion Nature on Electrochemical Reduction of Bismuth Sulfide in Nickel Plating Solution
| Autor: | A. Sudavičius, Loreta Tamašauskaitė-Tamašiūnaitė, Genovaitė Valiulienė, Albina Žielienė, Leonas Naruškevičius, Birutė Šimkūnaitė-Stanynienė |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
inorganic chemicals
lcsh:TN1-997 Materials science Inorganic chemistry Ionic bonding chemistry.chemical_element Electrolyte Quartz crystal microbalance Electrochemistry EQCM Nickel nickel Adsorption chemistry Plating bismuth sulfide XPS General Materials Science Cyclic voltammetry SILAR lcsh:Mining engineering. Metallurgy |
| Zdroj: | Medžiagotyra, Vol 17, Iss 1, Pp 27-31 (2011) |
| ISSN: | 2029-7289 1392-1320 |
| Popis: | The influence of anion nature on the reduction of bismuth sulfide film deposited on gold using the successive ionic layer adsorption and reaction method in solutions containing Ni2+ ions has been investigated by electrochemical quartz crystal microbalance combined with cyclic voltammetry and X-ray photoelectron spectroscopy. It has been determined that the reduction of bismuth sulfide film in the nickel plating solution depends on the anion nature: larger cathodic current and mass changes (Dƒ) are observed in the solution containing acetate anion as compared to those in the solution containing sulfate anion. As the reduction of bismuth sulfide film in the background solutions depends on the nature of anion, it influences the cathodic reduction of Ni2+ ions prior to OPD of Ni. A greater current and mass change (Dƒ) is conditioned by simultaneously occurring reduction of bismuth sulfide film when the film is reduced in the acetate nickel plating electrolyte in contrast to that in the sulfate one.http://dx.doi.org/10.5755/j01.ms.17.1.244 |
| Databáze: | OpenAIRE |
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