Synthesis of C–B–O five membered ring by hydroboration of allylalcohols in standard conditions
| Autor: | Ahmed Djellal, Samia Amirat |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Chemistry(all)
Chemistry Stereochemistry General Chemical Engineering Allylalcohol General Chemistry Ring (chemistry) lcsh:Chemistry Trimethylsilyloxy Hydroboration lcsh:QD1-999 Yield (chemistry) Chemical Engineering(all) GeneralLiterature_REFERENCE(e.g. dictionaries encyclopedias glossaries) ComputingMilieux_MISCELLANEOUS Oxaborolanes |
| Zdroj: | Arabian Journal of Chemistry, Vol 7, Iss 4, Pp 518-521 (2014) |
| ISSN: | 1878-5352 |
| DOI: | 10.1016/j.arabjc.2010.11.012 |
| Popis: | The hydroboration of protected allylalcohols by two different groups gives no linear structures of siloxypropylboranyls as predicted but gives the C–B–O five membered ring 1,2-H-oxaborolanes with good yield. A mechanism is also proposed to explain this cyclisation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|