Synthesis of Constrained C-Glycosyl Amino Acid Derivatives Involving 1,3-Dipolar Cycloaddition of Cyclic Nitrone as Key Step
| Autor: | Arnaud Martel, Florian Rouzier, Stéphane Guillarme, Gilles Dujardin, Rosanne Sillé, Arnaud Tessier, Arnaud Nourry, Muriel Pipelier, Ophélie Montiège |
|---|---|
| Přispěvatelé: | Institut des Molécules et Matériaux du Mans (IMMM), Le Mans Université (UM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation (CEISAM), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
C glycosides
chemistry.chemical_classification 010405 organic chemistry Chemistry Stereochemistry Organic Chemistry 010402 general chemistry 01 natural sciences Cycloaddition 0104 chemical sciences Amino acid Nitrone chemistry.chemical_compound 1 3-Dipolar cycloaddition [CHIM]Chemical Sciences Glycosyl Physical and Theoretical Chemistry |
| Zdroj: | European Journal of Organic Chemistry European Journal of Organic Chemistry, Wiley-VCH Verlag, 2020, ⟨10.1002/ejoc.202001162⟩ |
| ISSN: | 1434-193X 1099-0690 |
| DOI: | 10.1002/ejoc.202001162⟩ |
| Popis: | International audience; An efficient two-step strategy for the synthesis of constrained C-glycosyl amino acid derivatives from C-vinylglycosides involving a 1,3-dipolar cycloaddition using L-(-)menthone-derived nitrone as the key step is described. After optimization of 1,3-dipolar cycloaddition conditions, various C-vinylglycosides were tested leading exclusively to one dia-[a] |
| Databáze: | OpenAIRE |
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