Intramolecular Hydroamination of Selenoalkynes to 2-Selenylindoles in the Absence of Catalyst

Autor:	Paulo Fernando Bruno Gonçalves, Paulo H. Schneider, Felipe Lange Coelho, Eduarda Sangiogo Gil, Leandra Franciscato Campo
Rok vydání:	2019
Předmět:	Indole test 010405 organic chemistry Organic Chemistry chemistry.chemical_element Regioselectivity General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Chalcogen chemistry Intramolecular force Hydroamination Tellurium Derivative (chemistry)
Zdroj:	Chemistry (Weinheim an der Bergstrasse, Germany). 25(34)
ISSN:	1521-3765
Popis:	In this work, a series of 2-chalcogenylindoles was synthesized by an efficient methodology, starting from chalcogenoalkynes, including a previously unreported tellurium indole derivative. For the first time, these 2-substituted chalcogenylindoles were obtained in the absence of metal catalyst or base, under thermal conditions only. In addition, the results described herein represent a methodology with inverse regioselectivity for the chalcogen functionalization of indoles.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::228d37473eec60778c4d495d399d1af1 https://pubmed.ncbi.nlm.nih.gov/30985948 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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