| Autor: |
Tompkins, DC, Stewart, DI, Graham, JT, Burke, IT |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Journal of Hazardous Materials Advances. 5:100043 |
| ISSN: |
2772-4166 |
| Popis: |
The leaching behavior of stockpiled crushed concrete waste is important in determining its suitability for in situ disposal at UK nuclear sites. Sand sized particles from surface (0–0.1 m) and subsurface (2.5–2.7 m) samples were composed of silica and calcite grains in a matrix of calcium alumina-silicate hydrate (C-(A)-S-H) with Ca/Si ratios of 0.5 ±0.3 and 0.9 ±0.3 respectively. Calcite content was also higher in surface samples indicating a greater degree of weathering and carbonation. This resulted in lower leachate pH for the surface samples (pH 8–9.6) compared to subsurface samples (pH 10–11.3). The waste displayed a high acid buffering capacity but low alkaline buffering capacity. Element release as a function of pH was similar for surface and sub-surface samples and between different size fractions. Leaching of contaminant metals was close to minimum values at the pH values produced by the crushed concrete but increased by several orders of magnitude at pH 12 (for Al and Pb). Weathering and carbonation during long-term stockpiling, therefore, has a positive impact by producing a waste with stable pH and low metal leaching potential suitable for in-situ disposal as a void fill material. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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