3-(2,2,2-Trifluoroethoxy)propionitrile-based electrolytes for high energy density lithium metal batteries

Autor: Xin Zhou, Melania Kozdra, Qin Ran, Keqing Deng, Hu Zhou, Daniel Brandell, Jinglun Wang
Rok vydání: 2022
Předmět:
Zdroj: Nanoscale. 14(46)
ISSN: 2040-3372
Popis: In this study, 3-(2,2,2-trifluoroethoxy)-propionitrile (FEON), a fluorinated nitrile compound with high oxidative stability, low volatility and non-flammability, is introduced as an electrolyte solvent for high-energy density Li|NCM batteries. After optimization of the electrolyte as (0.8 M LiTFSI + 0.2 M LiODFB)/FEC : FEON (1 : 3, by vol., abbreviated as FF13), the FEON-based electrolyte exhibits better cycling performance for both the lithium metal anode and 4.4 V high-voltage NCM cathode, compared with those of a commercial carbonate electrolyte of 1 M LiPF
Databáze: OpenAIRE