Di-, tri- and tetraphosphine-substituted Fe/Se carbonyls: synthesis, characterization and electrochemical properties

Autor: Shu-Fen Bai, Xiu-Mei Du, Wen-Jing Tian, Hang Xu, Ru-Fen Zhang, Chun-Lin Ma, Yan-Lan Wang, Shuang Lü, Qian-Li Li, Yu-Long Li
Rok vydání: 2022
Předmět:
Zdroj: Dalton transactions (Cambridge, England : 2003). 51(29)
ISSN: 1477-9234
Popis: The active sites of [FeFe]-hydrogenase promoted by Fe/E (E = S, Se) clusters have attracted considerable interest due to their significance in understanding the interconversion of hydrogen with protons and electrons. As an extension of the study on Fe/Se clusters related to H-cluster model compounds of [FeFe]-hydrogenase, a series of tertiary phosphine substituted Fe/Se carbonyls were successfully prepared. The treatment of Fe
Databáze: OpenAIRE