Quantifying the Influence of Covalent Metal‐Ligand Bonding on Differing Reactivity of Trivalent Uranium and Lanthanide Complexes

Autor: Taylor V. Fetrow, Joshua Zgrabik, Rina Bhowmick, Francesca D. Eckstrom, George Crull, Bess Vlaisavljevich, Scott R. Daly
Rok vydání: 2022
Předmět:
Zdroj: Angewandte Chemie. 134
ISSN: 1521-3757
0044-8249
DOI: 10.1002/ange.202211145
Popis: Qualitative differences in the reactivity of trivalent lanthanide and actinide complexes have long been attributed to differences in covalent metal-ligand bonding, but there are few examples where thermodynamic aspects of this relationship have been quantified, especially with U
Databáze: OpenAIRE