Kinetics of the cathodic discharge of ammonium ion dissolved in dimethylsulfoxide on platinum

Autor:	Alejandro Jorge Arvia, C. Martinez, J.A. Wargon
Jazyk:	angličtina
Rok vydání:	1973
Předmět:	Reaction mechanism Hydrogen Chemistry General Chemical Engineering Inorganic chemistry chemistry.chemical_element Química Ion Solvent chemistry.chemical_compound Ammonia Adsorption Electrochemistry Ammonium ion Ammonium Platinum DMSO Cathodic discharge Ciencias Exactas
Zdroj:	SEDICI (UNLP) Universidad Nacional de La Plata instacron:UNLP
Popis:	The cathodic discharge of ammonium ion dissolved in DMSO solution on platinum electrodes in the temperature range from 25 to 44 °C yields ammonia and hydrogen at the ratio 2 : 1. The kinetics of the reaction was studied both under stationary and non-stationary conditions and reveals an influence of the treatment of the electrode surface. The kinetic parameters were interpreted with a reaction mechanism involving the participation of adsorption competition between either solvent or impurity molecules and hydrogen atoms, assuming the recombination of these adatoms is rate determining. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::21777f793069a6744413958ca13a4924 http://sedici.unlp.edu.ar/handle/10915/121896 Zobrazit plný text záznamu