Validation of a multiclass multiresidue method and monitoring results for 210 pesticides in fruits and vegetables by gas chromatography-triple quadrupole mass spectrometry

Autor:	Noelia Belmonte, Milagros Mezcua, Samanta Uclés, Miguel Gamón, Ana B. Martínez, Amadeo R. Fernández-Alba, M. Jesus Martinez-Bueno
Přispěvatelé:	Hydrosciences Montpellier (HSM), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement (IRD)-Université Montpellier 2 - Sciences et Techniques (UM2)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)
Rok vydání:	2014
Předmět:	Analyte Multiresidue methods GC-QQQ-MS Analytical chemistry Ethyl acetate fruits and vegetables 02 engineering and technology 01 natural sciences Gas Chromatography-Mass Spectrometry chemistry.chemical_compound Solanum lycopersicum Onions Vegetables [SDU.STU.HY]Sciences of the Universe [physics]/Earth Sciences/Hydrology Solanum tuberosum Chromatography Pesticide residue Chemistry Elution 010401 analytical chemistry Selected reaction monitoring Pesticide Residues pesticides General Medicine 021001 nanoscience & nanotechnology Pollution Backflush accounting 0104 chemical sciences monitoring Fruit Food Technology Gas chromatography Gas chromatography–mass spectrometry 0210 nano-technology Citrus sinensis Food Science
Zdroj:	Journal of Environmental Science and Health, Part B Journal of Environmental Science and Health, Part B, Taylor & Francis, 2014, 49 (8), pp.557--568. ⟨10.1080/03601234.2014.911566⟩
ISSN:	1532-4109 0360-1234
DOI:	10.1080/03601234.2014.911566
Popis:	International audience; A rapid, sensitive, accurate and reliable multiresidue method for the identification and quantification of 210 relevant pesticides in four representative fruit and vegetable commodities (tomato, potato, spring onion and orange) has been developed and validated by gas chromatography in tandem with triple quadrupole mass spectrometry. The method has been fully validated and applied to 292 samples from different countries. Prior to instrumental analysis, an extraction procedure based on a sample extraction of multiclass analytes, using the ethyl acetate method was employed. Mass spectrometric conditions were individually optimized for each compound in the selected reaction monitoring (SRM) mode to achieve maximum sensitivity. The pesticides were separated in less than 25 min. This was followed by an exhaustive control of the retention times. The Retention Time Locking Method was applied, working at a constant pressure throughout the analysis. System maintenance was reduced by using a purged capillary flow device that provided backflush capabilities by reversing column flow immediately after elution of the last compound of interest. Istotopically labelled internal standards were employed to improve the quality of the analytical results.
Databáze:	OpenAIRE
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