Highly Conjugated Bis(benzo[ b ]phosphole)‐ P ‐oxides: Synthesis and Electrochemical, Optical, and Computational Studies

Autor:	Nicolas D'Imperio, Valentina Pelliccioli, Sara Grecchi, Alberto Bossi, Francesca Vasile, Silvia Cauteruccio, Anna I. Arkhypchuk, Arvind Kumar Gupta, Andreas Orthaber, Sascha Ott, Emanuela Licandro
Rok vydání:	2022
Předmět:	Organisk kemi diastereomers Organic Chemistry pi-conjugation fluorescence Physical and Theoretical Chemistry benzophospholes cyclic voltammetry
Zdroj:	European Journal of Organic Chemistry. 26
ISSN:	1099-0690 1434-193X
DOI:	10.1002/ejoc.202201209
Popis:	The first examples of a pi-conjugated benzo[b]phosphole P-oxide in which two phosphole P-oxide units are connected by a carbon-carbon double bond are described. The molecules are synthesized as E isomers with respect to the carbon-carbon double bond and exist as stable cis and trans isomers (chiral and meso one respectively) relatively to the two stereogenic P atoms. The optical and electrochemical properties of both isomers have been investigated by experiment and computations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::21359dbd6617562bb6515ae4ccb61958 https://doi.org/10.1002/ejoc.202201209 Zobrazit plný text záznamu