Enabling Suzuki-Miyaura coupling of Lewis-basic arylboronic esters with a nonprecious metal catalyst

Autor: Michael C. Haibach, Andrew R. Ickes, Sergei Tcyrulnikov, Shashank Shekhar, Sebastien Monfette, Rafal Swiatowiec, Brian J. Kotecki, Jason Wang, Amanda L. Wall, Rodger F. Henry, Eric C. Hansen
Rok vydání: 2022
Předmět:
Zdroj: Chemical science. 13(43)
ISSN: 2041-6520
Popis: The high cost and negative environmental impact of precious metal catalysts has led to increased demand for nonprecious alternatives for widely practiced reactions such as the Suzuki-Miyaura coupling (SMC). Ni-catalyzed versions of this reaction have failed to achieve high reactivity with Lewis-basic arylboron nucleophiles, especially pinacolboron esters. We describe the development of (PPh
Databáze: OpenAIRE