Selective removal of phenyl group from alkyl diphenyl phosphates
| Autor: | Stanisław Witkowski, Piotr Wałejko |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
inorganic chemicals
Chemistry(all) information science Alkyl monophenyl phosphates 010402 general chemistry 01 natural sciences Medicinal chemistry chemistry.chemical_compound Acid sensitive Hydrogenolysis Phenyl group Organic chemistry Catalytic hydrogenation natural sciences GeneralLiterature_REFERENCE(e.g. dictionaries encyclopedias glossaries) ComputingMilieux_MISCELLANEOUS Alkyl chemistry.chemical_classification 010405 organic chemistry Alkyl diphenyl phosphates General Chemistry 0104 chemical sciences chemistry Yield (chemistry) Palladium catalyst |
| Zdroj: | Journal of Saudi Chemical Society. 21:118-122 |
| ISSN: | 1319-6103 |
| Popis: | Figure options Download full-size image Download high-quality image (34 K) Download as PowerPoint slide Selective removal of one phenyl group from alkyl diphenyl phosphates is reported. Catalytic hydrogenation on palladium catalyst (Pd/C) under atmospheric pressure provides the corresponding monophenyl phosphates in 70–89% yield. The method is efficient and mild, however, it cannot be applied for acid sensitive substrates. |
| Databáze: | OpenAIRE |
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