The suppression of superconductivity in MgCNi3 by Ni-site doping
Autor: | K. Inumaru, K. A. Regan, Robert J. Cava, Michael A. Hayward, M. K. Haas, Arthur P. Ramirez, T. He, N. Rogado |
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Jazyk: | angličtina |
Rok vydání: | 2016 |
Předmět: |
Superconductivity
Range (particle radiation) Materials science Condensed matter physics Condensed Matter - Superconductivity Doping Intermetallic Analytical chemistry FOS: Physical sciences General Chemistry Electron Condensed Matter Physics Magnetic susceptibility Superconductivity (cond-mat.supr-con) Materials Chemistry Solubility Perovskite (structure) |
DOI: | 10.1016/s0038-1098(01)00303-9 |
Popis: | The effects of partial substitution of Cu and Co for Ni in the intermetallic perovskite superconductor MgCNi3 are reported. Calculation of the expected electronic density of states suggests that electron (Cu) and hole (Co) doping should have different effects. For MgCNi3-xCux, solubility of Cu is limited to approximately 3% (x = 0.1), and Tc decreases systematically from 7K to 6K. For MgCNi3-xCox, solubility of Co is much more extensive, but bulk superconductivity disappears for Co doping of 1% (x = 0.03). No signature of long range magnetic ordering is observed in the magnetic susceptibility of the Co doped material. submitted, Solid State Communications |
Databáze: | OpenAIRE |
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