3D Carbon Frameworks for Ultrafast Charge/Discharge Rate Supercapacitors with High Energy-Power Density

Autor: Jieshan Qiu, Lulu Sun, Zhuangjun Fan, Yongzhen Yang, Xuzhen Wang, Zongbin Zhao, Changyu Leng, Yinzhou Song, Xuguang Liu
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nano-Micro Letters, Vol 13, Iss 1, Pp 1-11 (2020)
Nano-Micro Letters
ISSN: 2150-5551
2311-6706
DOI: 10.1007/s40820-020-00535-w
Popis: Highlights 3D carbon frameworks (3DCFs) constructed by interconnected nanocages show a high specific surface area, hierarchical porosity, and conductive network.The deoxidization process removed most of surface oxygen-containing groups in 3DCFs that leads to fast ion diffusion kinetics, good electric conductivity, and limited side reactions.The deoxidized 3DCFs exhibit an ultrafast charge/discharge rate as electrodes for SCs with high energy-power density in both aqueous and ionic liquids electrolytes. Electronic supplementary material The online version of this article (10.1007/s40820-020-00535-w) contains supplementary material, which is available to authorized users.
Carbon-based electric double layer capacitors (EDLCs) hold tremendous potentials due to their high-power performance and excellent cycle stability. However, the practical use of EDLCs is limited by the low energy density in aqueous electrolyte and sluggish diffusion kinetics in organic or/and ionic liquids electrolyte. Herein, 3D carbon frameworks (3DCFs) constructed by interconnected nanocages (10–20 nm) with an ultrathin wall of ca. 2 nm have been fabricated, which possess high specific surface area, hierarchical porosity and good conductive network. After deoxidization, the deoxidized 3DCF (3DCF-DO) exhibits a record low IR drop of 0.064 V at 100 A g−1 and ultrafast charge/discharge rate up to 10 V s−1. The related device can be charged up to 77.4% of its maximum capacitance in 0.65 s at 100 A g−1 in 6 M KOH. It has been found that the 3DCF-DO has a great affinity to EMIMBF4, resulting in a high specific capacitance of 174 F g−1 at 1 A g−1, and a high energy density of 34 Wh kg−1 at an ultrahigh power density of 150 kW kg−1 at 4 V after a fast charge in 1.11 s. This work provides a facile fabrication of novel 3D carbon frameworks for supercapacitors with ultrafast charge/discharge rate and high energy-power density. Electronic supplementary material The online version of this article (10.1007/s40820-020-00535-w) contains supplementary material, which is available to authorized users.
Databáze: OpenAIRE
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