Catalytic Dehydrogenative β-Alkylation of Amino Acid Schiff Bases with Hydrocarbon

Autor: Tetsu Ikeda, Haruka Ochiishi, Mana Yoshida, Ryo Yazaki, Takashi Ohshima
Rok vydání: 2021
Předmět:
Zdroj: Organic letters. 24(1)
ISSN: 1523-7052
Popis: A synthetic method for the synthesis of a highly congested α,β-dehydroamino acid through the β-C-H bond activation of an amino acid Schiff base is described. Abundant hydrocarbon feedstock could be used as an alkylating reagent to afford an α,β-dehydroamino acid bearing a quaternary carbon at the γ-position with an exclusively (
Databáze: OpenAIRE