Degradation of 4-Chlorophenol by Microwave-Enhanced Advanced Oxidation Processes: Kinetics and Influential Process Parameters
| Autor: | Kwinten Van Eyck, Raf Dewil, Hannah Milh |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
4-chlorophenol
microwave-enhanced AOP lcsh:Hydraulic engineering Geography Planning and Development Kinetics Analytical chemistry 02 engineering and technology 010501 environmental sciences Aquatic Science Kinetic energy 01 natural sciences Biochemistry chemistry.chemical_compound lcsh:Water supply for domestic and industrial purposes lcsh:TC1-978 Partial least squares regression Irradiation Hydrogen peroxide 0105 earth and related environmental sciences Water Science and Technology lcsh:TD201-500 021001 nanoscience & nanotechnology chemistry Scientific method Degradation (geology) 0210 nano-technology Microwave |
| Zdroj: | Water, Vol 10, Iss 3, p 247 (2018) Water; Volume 10; Issue 3; Pages: 247 |
| ISSN: | 2073-4441 |
| Popis: | In this study, the degradation of 4-chlorophenol (4-CP) is investigated by using a combination of microwave (MW) irradiation and hydrogen peroxide as oxidant (the MW–H2O2-process). The influence of the critical parameters on the efficiency of the process is examined by applying Partial Least Square Regression (PLS) on a Design of Experiments (DOE). Also, a kinetic evaluation of the process is carried out. Results showed that the MW–H2O2-process is effective in the degradation of 4-CP. The most influential parameter of the MW–H2O2-process is the reaction temperature. Besides this parameter, the reaction time, initial 4-CP concentration, and initial hydrogen peroxide concentration have a (minor) influence on the 4-CP degradation. A maximum degradation efficiency within the levels of the DOE (remaining percentage of 4-CP of 34%) was achieved with an initial 4-CP concentration of 1000 mg/L, an initial H2O2 concentration of 11 g/L, reaction temperature of 180 °C, and reaction time of 20 min. The process follows pseudo first order reaction kinetics. ispartof: Water - Basel vol:10 issue:3 pages:1-12 status: published |
| Databáze: | OpenAIRE |
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