On the study of the vibrational energy levels of Arsine molecule
| Autor: | Elena Sergeevna Bekhtereva, O.N. Ulenikov, Claude Leroy, N. Sanzharov |
|---|---|
| Přispěvatelé: | Laboratoire Interdisciplinaire Carnot de Bourgogne (LICB), Université de Bourgogne (UB)-Centre National de la Recherche Scientifique (CNRS), Lab Mol Spect, Dept Phys, Tomsk State University [Tomsk], Grant No. 2005-708 of the French Embassy in Moscow, Laboratoire Interdisciplinaire Carnot de Bourgogne ( LICB ), Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ) |
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: |
Unitary group approach
Vibrational energy [ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph] 02 engineering and technology 01 natural sciences Hot band chemistry.chemical_compound Arsine [PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph] Normal mode 0103 physical sciences Molecular symmetry Molecule Physical and Theoretical Chemistry 010306 general physics Spectroscopy Physics Vibrational excitations Local mode 021001 nanoscience & nanotechnology Atomic and Molecular Physics and Optics Vibration chemistry Molecular vibration AsH3 Atomic physics 0210 nano-technology |
| Zdroj: | Journal of Molecular Spectroscopy Journal of Molecular Spectroscopy, Elsevier, 2008, 247 (1), pp.1-24. ⟨10.1016/j.jms.2007.10.007⟩ Journal of Molecular Spectroscopy, Elsevier, 2008, 247 (1), pp.1-24. 〈10.1016/j.jms.2007.10.007〉 |
| ISSN: | 0022-2852 1096-083X |
| DOI: | 10.1016/j.jms.2007.10.007⟩ |
| Popis: | We compare two formalisms applied to the vibrational modes of the molecule of AsH 3 of C 3 v molecular symmetry group. Indeed, the close stretching modes of this molecule may be considered as those of a three-dimensional oscillator whereas the bending modes may be considered either as a one-dimensional oscillator of symmetry A 1 and a two-dimensional oscillator of symmetry E or as an approximate three-dimensional oscillator. So, we have applied the U ( p + 1) formalism to the both stretching and bending modes and introduced coupling terms acting on an appropriate coupled vibrational basis through a local mode formalism. We have then compared the result of our fitting with those obtained with the coupling of a local mode formalism adapted to the stretching vibrations with a normal mode formalism for the bending ones. Finally we compare our results with other methods recently proposed in the literature. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect