Intramolecular rotations and electronic states of iron in the iron bis(dicarbollide) complex $Fe[(C_{2}B_{9}H_{11})_{2}]$ studied by a $^{57}Fe$ nuclear probe and computational methods
| Autor: | Katarzyna Bednarska-Szczepaniak, Jan Stanek, Ewelina Przelazły, Zbigniew J. Lesnikowski, Katarzyna Dziedzic-Kocurek |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: |
Materials science
Metals and Alloys General Chemistry Electric charge Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Adduct Electronic states Crystallography Character (mathematics) Intramolecular force Mössbauer spectroscopy Materials Chemistry Ceramics and Composites Spin (physics) |
| Popis: | Mossbauer spectroscopy of iron(III)bis(dicarbollide) (1) and its adduct (2) revealed low spin FeIII in 1 and supprasingly FeII in 2. In 1 the (C2B9H11) rotate at room temperature with 107 Hz frequency getting across energy barrier of 24 meV. Numerical simulations shown a gradient of electric charge in 2 which may explain the FeII-like character in 2. |
| Databáze: | OpenAIRE |
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