Chemical evidence of the stability of praseodymium(v) in gas-phase oxide nitrate complexes
| Autor: | Bernardo Monteiro, Célia Lourenço, John K. Gibson, Joaquim Marçalo, Ana F. Lucena, Nuno A. G. Bandeira, José M. Carretas |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
010405 organic chemistry Praseodymium Metals and Alloys Oxide chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Gas phase chemistry.chemical_compound chemistry Nitrate Oxidation state Materials Chemistry Ceramics and Composites Physical chemistry Reactivity (chemistry) Chemical stability Quadrupole ion trap |
| Zdroj: | Chemical communications (Cambridge, England). 55(94) |
| ISSN: | 1364-548X |
| Popis: | The diverse gas-phase reactivity of [LnO2(NO3)2]− complexes with water (Ln = Ce, Pr, Nd), examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state. |
| Databáze: | OpenAIRE |
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