Stable single atomic silver wires assembling into a circuitry-connectable nanoarray
Autor: | Xiaolei Hu, Xiaoping Wang, Yaxin Chen, Yoshio Bando, Junxiao Chen, Dai-Ming Tang, Dongrun Xu, Xi Liu, Xingfu Tang, Jun Chen, Dmitri Golberg, Takashi Sekiguchi, Weiye Qu, Zhiwei Huang |
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Jazyk: | angličtina |
Rok vydání: | 2021 |
Předmět: |
Materials science
Science General Physics and Astronomy Insulator (electricity) 02 engineering and technology Electron 010402 general chemistry 01 natural sciences General Biochemistry Genetics and Molecular Biology Article Metal Delocalized electron Atomic orbital Thermal Physics::Atomic and Molecular Clusters Condensed Matter::Quantum Gases Multidisciplinary Nanoscale materials business.industry Nanowires General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences Nanoelectronics visual_art visual_art.visual_art_medium Optoelectronics Condensed Matter::Strongly Correlated Electrons Nanorod 0210 nano-technology business |
Zdroj: | Nature Communications Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021) |
ISSN: | 2041-1723 |
Popis: | Atomic metal wires have great promise for practical applications in devices due to their unique electronic properties. Unfortunately, such atomic wires are extremely unstable. Here we fabricate stable atomic silver wires (ASWs) with appreciably unoccupied states inside the parallel tunnels of α-MnO2 nanorods. These unoccupied Ag 4d orbitals strengthen the Ag–Ag bonds, greatly enhancing the stability of ASWs while the presence of delocalized 5s electrons makes the ASWs conducting. These stable ASWs form a coherently oriented three-dimensional wire array of over 10 nm in width and up to 1 μm in length allowing us to connect it to nano-electrodes. Current-voltage characteristics of ASWs show a temperature-dependent insulator-to-metal transition, suggesting that the atomic wires could be used as thermal electrical devices. One-dimensional atomic metal wires can exhibit useful properties distinct from their bulk equivalents; however they typically suffer from limited stability. Here, Chen et al create atomic silver wires which are stable and exhibit a temperature dependent metal to insulator transition. |
Databáze: | OpenAIRE |
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