Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day

Autor:	Luis M. Campos, Maria I. Montañez, Michael Malkoch, Anders Hult, Per Antoni, Maxwell J. Robb, Craig J. Hawker, Eva Malmström
Jazyk:	angličtina
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Addition reaction Polymers and Plastics Organic Chemistry Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Dendrimer 1 3-Dipolar cycloaddition Polymer chemistry Materials Chemistry Thiol Molecule Azide Ene reaction
Popis:	Dendrimer synthesis should not be tedious and time-consuming. By utilizing an AB2−CD2 approach and having orthogonal, “clickable” groups on each monomer, the time for dendrimer assembly can be drastically reduced. This was shown by preparation of a sixth generation dendrimer from starting monomer units in a single day.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1f95380ce07d8a05136af006a7594711 https://resolver.caltech.edu/CaltechAUTHORS:20180605-164810729 Zobrazit plný text záznamu