A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures
| Autor: | Ilia Korobkov, Bulat Gabidullin, Tomasz G. Witkowski, Muralee Murugesu, Elena Sebastiao, Gabriel Brunet |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Lanthanide
Scaffold Materials science 010405 organic chemistry Ligand Magnetism chemistry.chemical_element equipment and supplies 010402 general chemistry 01 natural sciences 0104 chemical sciences Ion Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Dysprosium Magnetic relaxation human activities |
| Zdroj: | Dalton Transactions. 47:11782-11787 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c8dt00146d |
| Popis: | A recently designed nitrogen-rich ligand is successfully applied as a scaffold for lanthanide ions to show that the intricate chemistry of energetic materials can be combined with other fields of research, including that of molecular magnetism. Herein, we report the synthesis of two different types of molecular architectures using a single ligand template, in which the discrete monomer exhibits single-molecule magnet-like behaviour along with two well-isolated modes of magnetic relaxation. |
| Databáze: | OpenAIRE |
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